N-(4-Chloro-2-nitrophenyl)-N-(methylsulfonyl)acetamide
نویسندگان
چکیده
منابع مشابه
Supramolecular structures of three isomeric 2-chloro-N-(nitrophenyl)nicotinamides.
Molecules of 2-chloro-N-(2-nitrophenyl)nicotinamide, C12H8ClN3O3, are linked by two C-H...O hydrogen bonds into a chain of edge-fused R(2)(2) (14) and (4)(4) (24) rings. In 2-chloro-N-(3-nitrophenyl)nicotinamide monohydrate, C12H8ClN3O3.H2O, the molecules are linked by a combination of N-H...O, O-H...O and O-H...N hydrogen bonds into a chain of edge-fused rings containing two distinct types of ...
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The title compound, C(16)H(12)ClFN(2)O(4), crystallizes with two mol-ecules in the asymmetric unit in which the dihedral angles between the mean planes of the two benzene rings are 65.1 (7) and 65.6 (6)°. In each mol-ecule, the nitro group displays rotational disorder over two orientations in a 0.503 (11):0.497 (11) ratio and the Cl atom is disordered in a 0.432 (5):0.568 (5) ratio. In one mol-...
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In the title compound, C(16)H(17)ClN(4)O(2), the aromatic ring is twisted slightly with respect to the plane of the diazene group [N-N-C-C torsion angle = -3.9 (4)°]. The NO(2) group is twisted by 16.2 (4)° relative to the aromatic ring. The two ethyl chains are positioned such that one ethyl chain lies above and the other below the ring.
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In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformations of the N-C bonds in the C-SO(2)-NH-C segment have gauche torsions with respect to the S=O bonds. Further, the conformation of the N-H bond is syn to the ortho-methyl group in the sulfonyl benzene ring. The torsion angle of the C-SO(2)-NH-C segment in the mol-ecule is 55.0 (2)°. The two benzene rings are tilted relative to each othe...
متن کامل2-Chloro-N-[4-chloro-2-(2-chlorobenzoyl)phenyl]acetamide
In the title compound, C(15)H(10)Cl(3)NO(2), an intra-molecular N-H⋯O hydrogen bond forms a six-membered ring and enforces an almost coplanar conformation for the acetamido group, the central benzene ring and the bridging carbonyl C-C(=O)-C group: the dihedral angles between the benzene ring and the acetamide and carbonyl C-C(=O)-C planes are 7.06 (11) and 7.17 (12)°, respectively. The dihedral...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808032157